June 2022
Volume 63, Issue 7
Open Access
ARVO Annual Meeting Abstract  |   June 2022
2-Hydrazino-4,6-dimethylpyrimidine (2-HDP) as a novel therapeutic for the neurovascular pathology of diabetic retinopathy
Author Affiliations & Notes
  • Josy Augustine
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Evan P Troendle
    Department of Chemistry, King's College London, London, United Kingdom
  • Thomas Friedel
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Eimear M Byrne
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Paul Canning
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Peter Barabas
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Martin B Ulmschneider
    Department of Chemistry, King's College London, London, United Kingdom
  • Alan W Stitt
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Tim M Curtis
    Wellcome-Wolfson Institute For Experimental Medicine, Queen's University Belfast, Belfast, United Kingdom
  • Footnotes
    Commercial Relationships   Josy Augustine None; Evan Troendle None; Thomas Friedel None; Eimear Byrne None; Paul Canning None; Peter Barabas None; Martin Ulmschneider None; Alan Stitt None; Tim Curtis None
  • Footnotes
    Support  Diabetes UK (18/0005791)
Investigative Ophthalmology & Visual Science June 2022, Vol.63, 2305. doi:
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      Josy Augustine, Evan P Troendle, Thomas Friedel, Eimear M Byrne, Paul Canning, Peter Barabas, Martin B Ulmschneider, Alan W Stitt, Tim M Curtis; 2-Hydrazino-4,6-dimethylpyrimidine (2-HDP) as a novel therapeutic for the neurovascular pathology of diabetic retinopathy. Invest. Ophthalmol. Vis. Sci. 2022;63(7):2305.

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      © ARVO (1962-2015); The Authors (2016-present)

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Abstract

Purpose : Diabetic retinopathy (DR) is a common neurovascular complication of diabetes. Retinal accumulation of the acrolein-derived advanced lipoxidation end-product, FDP-lysine (Nε-(3-formyl-3,4-dehydropiperidino-lysine), has been implicated in the pathogenesis of this condition. We have identified a new drug called 2-HDP that is effective in scavenging acrolein and preventing retinal FDP-lysine accumulation during diabetes. The aim of this study was to determine whether 2-HDP can protect against neurovascular dysfunction during diabetes.

Methods : Male Sprague-Dawley rats were divided into three groups: (1) non-diabetic; (2) streptozotocin-induced diabetic; and (3) diabetic treated with 2-HDP administrated in their drinking water. In vivo analysis of blood pressure, body weights, water intake, HbA1c and electroretinography (ERG) were measured at 1-,3- and 6-months after diabetes induction. Immunolabelling, western blotting, cytokine arrays and the Evan’s blue dye assay were carried out to study the vascular, neuronal, and glial components of the retina. Molecular Dynamics (MD) simulations were performed to investigate 2-HDP drug permeation across cellular membranes.

Results : ERG a- and b-wave amplitudes were significantly reduced in diabetic controls after 3- and 6-months of diabetes and these changes were completely prevented by treatment with 2-HDP (P<0.01). This drug also prevented retinal FDP-lysine accumulation, the activation of Müller cells and microglia, and neuro and vasodegenerative changes in the diabetic retina (P<0.05). MD simulations have revealed that most 2-HDP molecules are protonated and do not readily cross cell membranes.

Conclusions : Our studies provide strong evidence for a key role of acrolein and FDP-lysine in the development of the neurovascular lesions associated with DR.

This abstract was presented at the 2022 ARVO Annual Meeting, held in Denver, CO, May 1-4, 2022, and virtually.

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